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Electrodes and aluminizing
James Lerch
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----- Original Message -----
From: "Dominic-Luc Webb" <dlwebb@...> Well, if you want pre-finished ready to go Tungsten, try : Alternativly, I cut and form my own tungsten using bulk 0.032" wire from here: Another easy to scrounge source of Tungsten is from the Tig Welding Industry. (however it only comes in 150mm lengths, and can be somewhat expensive.) If you go with either the bulk Tungsten wire, or Tig Rod, before you try to Cut/Form the wire, you'll need to heat it past the "Ductile to Brittle Transition Tempature" At room temps, Tungsten is surprisingly brittle and any attempts to cut/bend will just snap it like a lead pencil. Fortunatly the ductile transition tempature starts at around 100c, once the wire is above this tempature it will bend / cut easily. I use a 2400watt hot air gun to pre-heat the tungsten before inserting into my filament mold. Perhaps someone knows there is in fact a reason to not use theseSeveral things to consider: #1 Wetting Action If you plan on using a wire filament, if the Al won't wet onto the filament material, it will just melt and fall off, and if the blob of liquid Al lands on a glass surface, it WILL FRACTURE the glass (been there, done that, makes for a VERY BAD DAY!) If your going to use a Boat / Box thermal source, then wetting action isn't important anymore. #2 Chemistry Al is amazingly reactive stuff, even when used with Tungsten, some of the Tungsten will disolve into the molten Al (cause of the wetting action?) As the Al evaporates, the Tungsten is re-deposited back onto the filament. If the filament is too small in diameter (compared to the amount of Al) dissolution of the tungsten into the Al will cause the filament to separate into two pieces, and evaporation quickly stops :-0 I tried using a heating element material used for HVAC (no idea what it was but probably not NiCr) and as soon as I applied power, the filament went "poof" into two rather small pieces. Based on the Al deposition data chart from Lesker's ( ) for a coil /wire thermal source, they only recomend Tungsten, for a boat they recomend Tungsten or Titanium-Boride. If you try NiCr or Kanthal, here are few thinkgs to consider. Al has a melting point of 660C, and a evaporation temp of 821C @ 10-6 torr. NiCr has a melting point of 1395C, while at the same time it appears to sublimate at 987C @ 10-6 torr. So if your chamber is at 10-6 torr, you'll need to keep the NiCr wire below 987C and above 660C, or you will end up with some form of NiCrAl film? Kanthal is another interesting species, its made from FeCrAl, the Al forms an Aluminum oxide which protects the FeCr from oxidation when used as a heating element. No data is listed for Kanthal's melting point or vapor pressure, so who knows what will happen :) BTW, I did find this interesting, Tungsten appears to sublimate at 2407C @ 10-6 torr, and of late, after the Al has evaporated off the Tungsten, I've been running the filament power up untill the Tungsten was white hot (why, no reason other than it's entertaining in an odd way). I mention this as I suddenly wonder if perhaps I might be sublimating a very thin film of Tungsten over the Al coat. If that's a good idea or not, I don't know.... James |
On Mon, 8 Dec 2003, James Lerch wrote:
Perhaps someone knows there is in fact a reason to not use theseSeveral things to consider: I was thinking about car cigarette light in these terms actually. I had idea to use a nozzle arrangement as an outlet above the heat source, such that the vapor would be forced to rise upward before encountering the nozzle which points downward in my tentative design. #2 Chemistry Great! That was the kind of value (821 C) I knew existed somewhere. NiCr has a melting point of 1395C, while at the same time it appears to This sublimation temp is indeed inferior to tungsten. So if your chamber is at 10-6 torr, you'll need to keep the NiCr wire below 987C Exactly! And this might even be highly reflective and less prone to oxidation. Kanthal is another interesting species, its made from FeCrAl, the Al forms anKanthal = Swedish product, so we we hear about it alot up here. There are different grades of this wire. I recall some very high temp versions when I was interested in higher melting point glass and ceramic materials years ago. The "Kanthal D" is likely the most famous (max temp 1300 C), but there is also "Kanthal Super", which has max temp 1700-1800 C. I'll attach the Kanthal Handbook in a private post (to James). BTW, I did find this interesting, Tungsten appears to sublimate at 2407C @ 10-6Immediate thought: If you need such high temperature, there is something seriously wrong with either the temperature reading or the pressure reading or the material you think is (reduced) aluminum. I see no hope for tungsten on the mirror to contribute positively. I am not totally committed on this statement, either. I am suspicious that rate of vaporization could be a factor, in which case your heat excess is an unavoidable consequence of achieving a desirable instant vaporization. To that end, perhaps the lower pressures I am getting, like below 10e-7 could be favorable. Any idea if there is a pressure that is too low (within reason for a diffusion pump)? Dominic-Luc Webb |
arcstarter
--- In VacuumX@..., Dominic-Luc Webb <dlwebb@c...> wrote:
actually. I hadI was thinking about car cigarette light in these terms idea to use a nozzle arrangement as an outlet above the heatsource, such that the vapor would be forced to rise upward before encounteringthe nozzle which points downward in my tentative design.As I understand - unless the walls of the nozzle are held at a temperature akin to that of the evaporating aluminum - the aluminum will stick to the nozzle walls and will not make the curve. Most references show line of sight propagation from the molten surface outwards, with no 'reflection' or other flow properties. The atoms stick to the first cold surface they reach. If your pressure is too high the hot freshly evaporated atoms will either react with or lose heat with (via collision) the other gas molecules, and one way or another will not stick to the target. As far as low pressure - the lower the better with 10e-6 Torr being a common goal for evaporation. That's about 1 billionth of atmospheric! -Bill |
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